Alolan Vulpix and Ninetales cannot be caught in Pokémon Legends: Arceus. The icy variant of the classic fire-fox Pokémon is a rarity in this game, but still obtainable through but one method.
You can obtain a single Alolan Vulpix from a late-game request. To get Alolan Ninetales, use an Ice Stone on Alolan Vulpix.
Request 83: Snow-White Vulpix in the Snow
You’ll need to hunt down five precious Vulpixes to claim one for yourself.
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Once you’ve found all five, just head back to the man who gave you the quest to receive your own Alolan Vulpix.
For a more in-depth guide on finding the five Alolan Vulpixes, go check outWhere to find all the hidden Alolan Vulpixes in Alabaster Icelands | Pokémon Legends: Arceuson Pro Game Guides!